| A Novel Fused Phosphorus Heterocycle: 4-(1'''',2'''',3'''',4-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2''''-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative |
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| 引用本文： | Jun Min HUANG*,Hui CHEN,Ru Yu CHEN Institute of Elemento-Organic Chemistry,National Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin 300071. A Novel Fused Phosphorus Heterocycle: 4-(1'''',2'''',3'''',4-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2''''-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative[J]. 中国化学快报, 2002, 0(2) |
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| 作者姓名： | Jun Min HUANG* Hui CHEN Ru Yu CHEN Institute of Elemento-Organic Chemistry National Laboratory of Elemento-Organic Chemistry Nankai University Tianjin 300071 |
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| 作者单位： | Jun Min HUANG*，Hui CHEN，Ru Yu CHEN Institute of Elemento-Organic Chemistry，National Laboratory of Elemento-Organic Chemistry，Nankai University，Tianjin 300071 |
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| 基金项目： | The project was supported by the National Natural Science Foundation of China and Foundation for University Key Teacher by the Ministry of Education. |
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| 摘 要： | Organophosphorus compounds are ubiquitous in nature and they have broad applications in the fields of agriculture and medicine1-4. There has been a considerably growing interest in heterocyclic compounds due to their pharmaceutical importance and extensive application in organic synthesis, and the application of heterocycles is suggested to enhance the biological activity and/or offer other diverse properties5-7. In the previous work8, we have reported that 11-ethoxycarbonylmethyl-6-oxo-3, 4…
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A Novel Fused Phosphorus Heterocycle: 4-(1'''',2'''',3'''',4-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2''''-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative |
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| Jun Min HUANG,Hui CHEN,Ru Yu CHEN Institute of Elemento-Organic Chemistry,National Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin. A Novel Fused Phosphorus Heterocycle: 4-(1'''',2'''',3'''',4-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2''''-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative[J]. Chinese Chemical Letters, 2002, 0(2) |
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| Authors: | Jun Min HUANG Hui CHEN Ru Yu CHEN Institute of Elemento-Organic Chemistry National Laboratory of Elemento-Organic Chemistry Nankai University Tianjin |
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| Affiliation: | Jun Min HUANG*,Hui CHEN,Ru Yu CHEN Institute of Elemento-Organic Chemistry,National Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin 300071 |
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| Abstract: | The first example of fused phosphorus heterocyclic 4-[1-(b-bromoethyl)-4-oxo-3-prop yl-1, 2, 3, 4-tetrahydro-1, 3, 2-benzodiazaphosphorin-2-sulfide]-1, 2, 3, 4, 4a, 4b, 5, 6-octahydro -6-oxo-5-propyl-3, 4b, 4a-thiazphosphaphenanthridine 4a, 2-dioxide was synthesized in excellent yield by refluxing a mixture of 1-(2-bromoethyl)-2, 3-dihydro-3-propyl-1, 3, 2-benzodiazaphos phorin-4(1H)-one 2-oxide with carbon disulfide in benzene in the presence of triethylamine. |
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| Keywords: | Synthesis [3 4b 4a] thiazphosphaphenanthridine. |
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