The effect of the cathode material on the electrochemical activation and dehalogenation of C-2 freons |
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| Authors: | V. E. Titov A. M. Mishura V. G. Koshechko |
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| Affiliation: | (1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine |
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| Abstract: | The effect of the cathode material (GC, Pt, Ag) on the electrophilic dehalogenation of C-2 Freons [F113 (CF2ClCFCl2), F113B2 (CF2BrCFClBr), and F114B2 (CF2BrCF2Br)] was studied. Such reactions lead to the formation of valuable chlorotrifluoro-or tetrachloroethylenes. It was found that a silver cathode has a promoting effect on the investigated processes compared with the other materials (GC, Pt). The optimum reaction conditions within the present investigation were determined. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 42, No. 4, pp. 217–221, July–August, 2006. |
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| Keywords: | Freons electrochemical activation electrosynthesis of fluoroethylenes |
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