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| 两个新颖原子簇化合物的合成及三价非线性光学吸收性质 | |
| 引用本文： | 侯红卫,忻新泉,宋连卿,樊耀亭. 两个新颖原子簇化合物的合成及三价非线性光学吸收性质[J]. 化学学报, 2000, 58(3): 283-286 |
| 作者姓名： | 侯红卫 忻新泉 宋连卿 樊耀亭 |
| 作者单位： | 1. 郑州大学化学化工学院,郑州,450052 2. 南京大学化学化工学院,南京,210093 3. 河南教育学院化学系,郑州,450003 |
| 摘 要： | 通过低热固相反应,我们合成了蝶型簇合物[MoOS~3Cu~2(PPh~3)~2(Py)~2](1),该簇合物与PPh~3反应,可以得到另一个新的簇合物[MoOS~3Cu~2(PPh~3)~3(Ph)](2)。使用Z-扫描方法测试这两个化合物的三阶非线性光学性质,发现它们都有较强的非线性光学吸收性质,非线性光学吸收系数分别是1.5×10^-^1^1mW^-^1和3.3×10^-^1^0mW^-^1。 |
| 关 键 词： | 原子簇 非线性光学 吸收系数 钼化合物 硫化合物 |
| 修稿时间： | 1999-04-14 |
Synthesis and third-order nonlinear optical absorptive properties of two novel cluster compounds |
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| HOU Hong-wei,XIN Xin-Quan,SONG Lian-Qing,FAN Yao-Ting. Synthesis and third-order nonlinear optical absorptive properties of two novel cluster compounds[J]. Acta Chimica Sinica, 2000, 58(3): 283-286 | |
| Authors: | HOU Hong-wei XIN Xin-Quan SONG Lian-Qing FAN Yao-Ting |
| Abstract: | Butterfly-shaped cluster [MoOS~3Cu~2(PPh~3)~2(Py)~2](1) has been synthesized by low-heating solid state reaction. Another new cluster [MoOS~3Cu~2(PPh~3)~3(Ph)](2) is obtained by the reaction of cluster (1) with PPh~3. Both clusters exhibit good nonlinear optical (NLO) absorptive properties. Their NLO absorptive indices are 1.5×10^- ^1^1mW^-^1 and 3.3×10^-^1^0mW^-^1 respectively. |
| Keywords: | cluster compounds synthesis nonlinear optical absorptive property |
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