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2D water layer enclathrated between Mn(II)-Ni(CN)4 coordination frameworks |
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| Authors: | Ambarish Ray Indrani Bhowmick Atish Dipankar Jana Mahammed Ali |
| Institution: | a Department of Chemistry, Jadavpur University, Kolkata 700 032, India b Lehrstuhl fur Analytischie Chemie, Ruhr-Universitat Bochum, D-44780, Bochum, Germany c Department of Physics, Sripat Singh College, Jiaganj, W.B. 742 123, India |
| Abstract: | A Ni(CN)4]2−-based two-dimensional Mn(II) coordination polymer {Mn(H2O)2NiCN]4·4H2O}, in which the coordination layers are stacked on top of each other sandwiching 2D water layer of boat-shaped hexagonal water clusters has been synthesized. The complex exhibits high thermal decomposition temperature and reversible water absorption, which were clearly demonstrated by thermal and PXRD studies on the parent and rehydrated complex after dehydration. |
| Keywords: | 2D coordination polymer 2D ice layer Boat-shaped hexagonal water clusters Reversible water adsorption High thermal stability |
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