| [Ni(C6H4N2)(CHC6H4O)2]配合物晶体结构及性质 |
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| 引用本文： | 王军,卑凤利,马卫兴,杨绪杰,陆路德,汪信. [Ni(C6H4N2)(CHC6H4O)2]配合物晶体结构及性质[J]. 无机化学学报, 2003, 19(6): 609-612 |
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| 作者姓名： | 王军 卑凤利 马卫兴 杨绪杰 陆路德 汪信 |
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| 作者单位： | 1. 南京理工大学材料化学实验室,南京,210094;江苏警官学院公安科技系,南京,210012
2. 南京理工大学材料化学实验室,南京,210094 |
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| 基金项目： | 江苏省自然科学基金资助项目(No.BK2002100)。 |
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| 摘 要： | The complex has been synthesized and characterized by spectroscopic techniques and single-crystal X-ray analysis. The crystal is orthorhombic ， space group P212121 with a=1.6620(3)nm， b=1.7300(4)nm， c=0.5450(1)nm and Z=4. In the crystal lattice， the molecules create a two-dimensional network structure through hydrogen bonds. The C-H…O intermolecular hydrogen bonds connect the title complex to form layer super-molecular plane structure perpendicular to the axis b， with the layers stacked by the Van der Waals interaction. CCDC： 195309.
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| 关 键 词： | 镍配合物 水杨醛 邻苯二胺 晶体结构 席夫碱 |
Crystal Structure and Some Properties of 1, 2-N,N-Disallicydene-Phenylamineato Nickel(Ⅱ) Complex |
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| WANG Jun,BEI Feng-Li,MA Wei-Xing,YANG Xu-Jie,LU Lu-De and WANG Xin. Crystal Structure and Some Properties of 1, 2-N,N-Disallicydene-Phenylamineato Nickel(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, 2003, 19(6): 609-612 |
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| Authors: | WANG Jun BEI Feng-Li MA Wei-Xing YANG Xu-Jie LU Lu-De WANG Xin |
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| Abstract: | The complex has been synthesized and characterized by spectroscopic techniques and single-crystal X-rayanalysis. The crystal is orthorhombic , space group P212121 with a = 1. 6620(3) nm, b = 1. 7300(4) nm, c =0. 5450( 1 ) nm and Z = 4. In the crystal lattice, the molecules create a two-dimensional network structure throughmolecular plane structure perpendicular to the axis b, with the layers stacked by the Van der Waals interaction. |
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| Keywords: | nickel?complex salicylaldehyde o phenylenediamine crystal structure Schiff base |
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