Formation of [Ar*Ge(CH2C(Me)C(Me)CH2)CH2C(Me)=]2 (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne |
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| Authors: | Stender Matthias Phillips Andrew D Power Philip P |
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| Institution: | Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California 95616, USA. |
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| Abstract: | The reduction of Ar*GeCl (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) with one equivalent of potassium leads to the formation of a germanium analogue of an alkyne Ar*GeGeAr* 1; reaction of 1 with 2,3-dimethyl-1,3-butadiene yields Ar*Ge(CH2C(Me)C(Me)CH2)CH2C(Me)=]2 2, which was structurally characterized. |
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