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Synthesis of macrocyclic compounds that are condensed with a pyrazole ring
Authors:Ya. L. Gol'dfarb  S. Z. Taits  E. A. Krasnyanskaya
Affiliation:(1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, 117913 Moscow
Abstract:2-Carbethoxy-[11]-agr-cyclothien-1-one, 2-carbethoxycyclopentadecanone, and 2,15-dicarbethoxy-[9,9]-agr-cyclodithiene-1,14-dione were converted to 2-phenyl-1-methyl-[11]-agr-cyclothieno [1,2-d] pyrazol-3-one, 2-phenyl-1-methyl-4,5-tridecamethylenepyrazol-3-one, and 2,16-diphenyl-1, 15-dimethyl- [9,9]-agr, agr prime-cyclodithienobis [(1,2-d, 14,15-dprime) pyrazole]-3,17-dione, respectively, by condensation with phenylhydrazine and subsequent methylation.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 920–923, July, 1980.
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