| 六(甲氧基乙氧基乙氧基)三聚磷腈的合成与表征 |
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| 引用本文： | 殷跃凡,黄荣,李艳梅,毕韵梅. 六(甲氧基乙氧基乙氧基)三聚磷腈的合成与表征[J]. 化学研究与应用, 2007, 19(3): 258-260 |
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| 作者姓名： | 殷跃凡 黄荣 李艳梅 毕韵梅 |
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| 作者单位： | 云南师范大学化学化工学院,云南,昆明,650092;云南大学化学科学与工程学院,云南,昆明,650031 |
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| 基金项目： | 国家自然科学基金(20364002)资助项目，中国科学院“西部之光”人才培养计划资助项目，云南省自然科学基金(2005B0027M)资助项目 |
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| 摘 要： | 以六氯三聚磷腈和甲氧基乙氧基乙醇为主要原料,合成了全取代的六(甲氧基乙氧基乙氧基)三聚磷腈,并用IR、31P NMR、1HNMR、13C NMR、FABMS等现代谱学技术对其结构进行了表征。经生物活性试验证明,此化合物对腐生线虫Panagrellus redivivus具有一定的毒杀活性。
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| 关 键 词： | 六(甲氧基乙氧基乙氧基)三聚磷腈 甲氧基乙氧基乙醇 合成 |
| 文章编号： | 1004-1656(2007)03-0258-03 |
| 修稿时间： | 2006-08-16 |
Synthesis and characterization of hexa (methoxyethoxyethoxy)cyclotriphosphazene |
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| YIN Yue-fan,HUANG Rong,LI Yan-mei,BI Yun-mei. Synthesis and characterization of hexa (methoxyethoxyethoxy)cyclotriphosphazene[J]. Chemical Research and Application, 2007, 19(3): 258-260 |
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| Authors: | YIN Yue-fan HUANG Rong LI Yan-mei BI Yun-mei |
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| Abstract: | Synthesis,characterization and biological activity of hexa(methoxyethoxyethoxy)cyclotriphosphazene,a new small-molecule phosphazene were described.The reaction of methoxyethoxyethanol with sodium hydride yielded sodium methoxy-ethoxyethanol.The title compound was prepared by nucleophilic substitution reaction of hexachlorocyclotriphosphazene with sodium methoxyethoxy-ethanol.Its structure was characterized by IR,31P NMR,1H NMR,13C NMR and FABMS.The experiment of the nematicidal activitity was carried out.The obtained results showed that the compound was able to kill 32.8% of the Panagrellus redivivus at 1mg/mL within 72 hours. |
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| Keywords: | hexa(methoxyethoxyethoxy)cyclotriphosphazene methoxyethoxy ethanol synthesis |
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