Radical-type reactivity of the 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyl |
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| Authors: | Amii Hideki Vranicar Lidija Gornitzka Heinz Bourissou Didier Bertrand Guy |
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| Affiliation: | Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse Cedex 04, France. |
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| Abstract: | Despite through-space and through-bond B-B interactions, the stable 1,3-bora-2,4-diphosphoniocyclobutane-1,3-diyl displays some radical-type behavior, as illustrated by the spontaneous formation of the trans 1,3-adduct with trimethyltin hydride and a B-spiro derivative with bromotrichloromethane. |
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