Pd-C-induced catalytic transfer hydrogenation with triethylsilane |
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| Authors: | Mandal Pijus K McMurray John S |
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| Affiliation: | Department of Experimental Therapeutics, The University of Texas M. D. Anderson Cancer Center, 1515 Holcombe Blvd., Houston, Texas 77030, USA. |
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| Abstract: | In situ generation of molecular hydrogen by addition of triethylsilane to palladium-charcoal catalyst results in rapid and efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection under mild, neutral conditions. |
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