An ESCA study of organosilicon compounds |
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Authors: | RC Gray JC Carver DM Hercules |
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Institution: | Department of Chemistry, University of Georgia, Athens, Georgia 30602 U.S.A. |
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Abstract: | The silicon 2p electron binding energies have been measured for a series of 33 organosilicon compounds. The binding energies are correlated with partial atomic charges calculated by various electronegativity models and CNDO calculations. Group shifts are reported for various chemical groups attached to silicon and are found to correlate with group shifts reported for carbon and phosphorus compounds. |
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