Photoelectron spectra of carbonyls,carbonates, oxalates and esterification effects |
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Authors: | S.P. McGlynn J.L. Meeks |
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Affiliation: | The Coates Chemical Laboratories, The Louisiana State University, Baton Rouge, Louisiana 70803 U.S.A.;Department of Chemistry, Cumberland College, Williamsburg, Kentucky 40769 U.S.A. |
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Abstract: | Photoelectron spectra are reported for dimethyl carbonate, ethylene carbonate, oxalic acid, dimethyl oxalate and diethyl oxalate. These spectra are discussed on a composite molecule basis using CNDO/s computational data and many of the individual bands are identified. The differential effects of esterification on ionization energies are discussed briefly. |
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