Hybrid compounds of Schiff base Cu,Fe, Co complexes with molybdovanadophoric heteropolyacids: synthesis,characterization and their catalytic performance to hydroxylation of benzene with H2O2 |
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| Authors: | Lijuan Chen Yujun Xiang Tao Feng |
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| Institution: | 1. School of Chemical Engineering and Chemistry, Hunan University of Science and Technology, , Xiangtan, China;2. Key Laboratory of Theoretical Chemistry and Molecular Simulating, Hunan Province and Ministry of Education, , China;3. School of Life Science, Hunan University of Science and Technology, , Xiangtan, China;4. School of Energy, Hunan University of Science and Technology, , Xiangtan, China |
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| Abstract: | Hybrid compounds of molybdovanadophoric heteropolyacids and a Schiff base transition metal complex, M‐saldmp or M‐fpdmp (M = Fe(II), Co(II), Cu(II)), were successfully prepared and found to be effective catalysts for direct hydroxylation of benzene with H2O2. The synergistic effect between Schiff base metal complex and heteropolyacid plays an important role in the promotion of catalytic activity. Copyright © 2012 John Wiley & Sons, Ltd. |
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| Keywords: | heteropolyacid Schiff base hydrogen peroxide phenol hydroxylation synergistic effect |
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