ZnI2‐promoted homologation of ferrocenylacetylene and aldehydes: an efficient synthesis of ferrocene‐containing allenes |
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Authors: | Shufeng Chen Jinxiang Shi Binglong Wang Haiying Zhao Baoguo Li |
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Affiliation: | College of Chemistry and Chemical Engineering, Inner Mongolia University, , Hohhot, 010021 China |
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Abstract: | A concise and efficient protocol for the first synthesis of ferrocene‐containing allenes based on the homologation reaction of ferrocenylacetylene and aldehydes promoted by ZnI2 was developed. The present method was applicable to many kinds of substituted aldehydes, providing good to excellent yields of ferrocene‐containing allenes. Copyright © 2012 John Wiley & Sons, Ltd. |
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Keywords: | ferrocenyl allenes homologation ferrocenylacetylene aldehydes catalysis |
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