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ZnI2‐promoted homologation of ferrocenylacetylene and aldehydes: an efficient synthesis of ferrocene‐containing allenes
Authors:Shufeng Chen  Jinxiang Shi  Binglong Wang  Haiying Zhao  Baoguo Li
Affiliation:College of Chemistry and Chemical Engineering, Inner Mongolia University, , Hohhot, 010021 China
Abstract:A concise and efficient protocol for the first synthesis of ferrocene‐containing allenes based on the homologation reaction of ferrocenylacetylene and aldehydes promoted by ZnI2 was developed. The present method was applicable to many kinds of substituted aldehydes, providing good to excellent yields of ferrocene‐containing allenes. Copyright © 2012 John Wiley & Sons, Ltd.
Keywords:ferrocenyl allenes  homologation  ferrocenylacetylene  aldehydes  catalysis
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