Synthesis of santiagonamine |
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Authors: | Markey Michael D Fu Ying Kelly T Ross |
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Institution: | E.F. Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, USA. |
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Abstract: | The first total synthesis of santiagonamine (1) is achieved in 12 steps from isovanillin. A palladium-catalyzed Ullmann cross-coupling reaction and a photocyclization are the key steps in the synthesis. |
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