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Rapid and sensitive spectrofluorimetric determination of trace amounts of Hg(II) with o-vanillin-8-aminoquinoline
Authors:F Yang  T X Yue  K H Xu  Z Z Chen  B Tang
Institution:(1) College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan, 250014, China
Abstract:The fluorimetric determination of mercury ions with o-vanillin-8-aminoquinoline (OVAQ) in aqueous solutions was investigated. Hg(II) could react with the fluorescent reagent OVAQ (λex/em = 278/314 nm) to form a nonfluorescent complex in an ethanol-water medium of pH 6.00. The linear range of the proposed method was from 2.5 to 80 μg/L, and the detection limit was 0.80 μg/L. The interferences of 24 foreign ions were also studied. The method was successfully applied to the determination of Hg(II) in sludge. The text was submitted by the authors in English.
Keywords:determination of Hg(II)  O-vanillin-8-aminoquinoline  spectrofluorimetry  quenching
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