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The first synthesis of tetraglucosyl glucitol having phytoalexin-elicitor activity in rice cells based on a sequential glycosylation strategy
Authors:Toru Amaya  Hiroshi Tanaka  Takeshi Yamaguchi  Naoto Shibuya  Takashi Takahashi  
Institution:

aDepartment of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8552, Japan

bBiochemistry Department, Institute of Plant Sciences, National Institute of Agrobiological Sciences, 2-1-2 Kannondai, Tsukuba, Ibaraki 305-8602, Japan

Abstract:We describe a highly convergent approach for the synthesis of the tetraglucosyl glucitol 1 and its derivatives 4, 5 and 6 which exhibit phytoalexin-elicitor activity in rice cells based on sequential glycosylation.
Keywords:β-glucan  phytoalexin elicitor  branched oligosaccharide  sequential glycosylation  thioglyciside
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