| 用分光光度法研究[Fe(H2O)3(NCS)3](18-C-6)在微栅电极上的电化学性质 |
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| 引用本文： | 李海英,郁章玉,李春英,顾登平.用分光光度法研究[Fe(H2O)3(NCS)3](18-C-6)在微栅电极上的电化学性质[J].物理化学学报,1990,6(6):735-738. |
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| 作者姓名： | 李海英 郁章玉 李春英 顾登平 |
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| 作者单位： | Department of Chemistry; Hebei Normal University; Shijiazhuang |
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| 摘 要： |
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| 关 键 词： | 铁配合物 冠醚 水 NCS 电化学性质 |
| 收稿时间： | 1989-08-26 |
| 修稿时间： | 1990-03-26 |
STUDIES ON THE ELECTROCHEMICAL BEHAVIORS OF [Fe(H2O)3(NCS)3] (18-C-6) ON MINIGRID ELECTRODE BY SPECTROPHOTOMETRY |
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| Li Hai-Ying,Yu Zhang-Yu,Li Chun-Ying,Gu Deng-Ping.STUDIES ON THE ELECTROCHEMICAL BEHAVIORS OF [Fe(H2O)3(NCS)3] (18-C-6) ON MINIGRID ELECTRODE BY SPECTROPHOTOMETRY[J].Acta Physico-Chimica Sinica,1990,6(6):735-738. |
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| Authors: | Li Hai-Ying Yu Zhang-Yu Li Chun-Ying Gu Deng-Ping |
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| Institution: | Department of Chemistry; Hebei Normal University; Shijiazhuang |
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| Abstract: | The electrochemical reduction processes of Fe(H_2O)_3(NCS)_3] (18-C-6) have been studied in nonaqueous media by method of cyclic voltammetry and spectroelec-trochemistry at an optical transparent thin layer electrode. The formal potential, E°′, electron transfer number, n, diffusion cofficient, D_O, formal heterogeneous electron transfer rate constant, k_S′, and electrochemical transfer coefficient, a, are deter-minated. Significant effect of solvents on the electrochemical behaviors has been observed. The higher the β, the higher the thermodynamic and kinetic stabilities of the coordination compound resulted. |
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