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Van der Waals radii of elements from the data of structural inorganic chemistry
Authors:S S Batsanov
Institution:(1) The Center High Dynamic Pressures of the Scientific Institute of Physicotechnical and Radiotechnical Measurements, Russian Academy of Sciences, 141570 Mendeleevo, Moscow Region, Russian Federation
Abstract:Van der Waals radii of elements were determined from the data of the structural inorganic chemistry: from intersitial distances in CdX2- and graphite-type structures, bond lengths in van der Waals molecules, molar volumes of A2-type substances, refractometry data, and from quantum chemical and correlation ratios. The recommended values of van der Waals radii of elements are tabulated.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 24–29, January, 1995.The author is grateful to the administration of the Department of Chemistry at the University of Durham (Great Britain) for the opportunity to perform this work and to Prof. J. Howard and Prof. K. Wade for useful discussions.
Keywords:molecules  anions  van der Waals radii  structure  molar volume  polarizability
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