Photoinduced phase transition of coordinationally unsaturated d9 metal centers within the thermal hysteresis of the spin exchange interaction |
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| Authors: | Naumov Pance Sakurai Kenji Asaka Toru Belik Alexei A Adachi Shin-ichi Takahashi Junichi Koshihara Shin-ya |
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| Institution: | ICYS, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan. naumov.pance@nims.go.jp |
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| Abstract: | Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers is affected by excitation of the LMCT bands within the hysteresis region of the low-temperature ferromagnetic-to-antiferromagnetic phase transition. |
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