Manganese complexes of 1,3,5-triaza-7-phosphaadamantane (PTA): the first nitrogen-bound transition-metal complex of PTA |
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| Authors: | Frost Brian J Bautista Carolyn M Huang Rongcai Shearer Jason |
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| Institution: | Department of Chemistry, MS 216, University of Nevada, Reno, Nevada 89557, USA. |
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| Abstract: | The structures of two manganese(II) complexes of 1,3,5-triaza-7-phosphaadamantane (PTA) reveal the first transition-metal complexes of PTA in which the metal preferentially coordinates to a nitrogen and not the phosphorus of PTA. The coordination environment about the manganese was probed using X-ray crystallography (solid state) and EXAFS spectroscopy (solution). |
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