Rate sensitivity analysis of a model of the Briggs-Rauscher reaction |
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Authors: | T. Turányi |
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Affiliation: | (1) Central Research Institute for Chemistry of the Hungarian Academy of Sciences, P.O. Box 17, H-1525 Budapest, Hungary |
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Abstract: | An updated mechanism for the Briggs-Rauscher reaction (also known as Iodine Clock reaction) has been investigated by the principal component analysis of the rate sensitivity matrix. The analysis revealed that five reactions of the 15-step model were redundant. The results of principal component and of rate-of-production analyses together gave an insight into the basic processes of the Iodine Clock reaction.
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