Characteristics of adsorption phase with water/organic mixtures at a surface of activated carbons possessing intraparticle and textural porosities |
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Authors: | V.M. Gun&rsquo ko,V.V. Turov,D. Palijczuk,S.V. Kerus,E.M. Pakhlov |
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Affiliation: | a Institute of Surface Chemistry, 17 General Naumov Street, 03164 Kiev, Ukraine b MAST Carbon Technology Ltd., Henley Park, Guildford, Surrey GU3 2AF, UK c Military Institute of Chemistry and Radiometry, 00-910 Warsaw, Poland |
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Abstract: | The behaviour of water and water/organic mixtures adsorbed onto activated microporous carbons or a carbon adsorbent with narrow intraparticle micropores and broad mesopores and macropores between nanoparticles was studied using low-temperature adsorption method and 1H NMR spectroscopy with layer-by-layer freezing-out of liquids at 190-273 K. These investigations revealed concentration-dependent effects of benzene, DMSO, acetone, chloroform, methane and acetonitrile on the characteristics of adsorbed water and the influence of this water on the interfacial behaviour of adsorbed organics. The influence of organics causes the structural and energetic differentiations of adsorbed water. The latter can be displaced by organics from micropores into broader pores and/or form mixture with polar solvents in meso and macropores. Freezing of adsorbed water can affect the adsorbent structure because ice crystallites have a larger size than that of liquid water droplets that lead to changes in the behaviour of adsorbed water/organic mixtures observed by the 1H NMR and adsorption methods. |
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Keywords: | 61.43.Gt Powders, porous materials 68.08.-p Liquid-solid interfaces 68.43.-h Chemisorption/physisorption: adsorbates on surfaces 68.35.Md Surface thermodynamics, surface energies 68.43.Vx Thermal desorption |
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