Solvent effects on solution enthalpies of adamantyl derivatives |
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| Authors: | Filomena Martins Luís Moreira Nélson Nunes Ruben E. Leitão |
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| Affiliation: | 1.Department of Chemistry and Biochemistry, Faculty of Sciences,University of Lisbon, CQB,Lisbon,Portugal;2.Instituto Superior de Educa??o e Ciências, CQB,Lisbon,Portugal;3.Department of Chemical Engineering,Engineering Institute (ISEL), Polytechnic Institute of Lisbon, CQB,Lisbon,Portugal |
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| Abstract: | Solution enthalpies of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone in a large set of protic and aprotic solvents are reported at 298.15 K. Solvent effects on the solution processes of these solutes are analyzed in terms of a modified TAKA equation, involving δcav h s as the cavity term. The nature and magnitude of the major interactions which influence these processes are assessed and discussed in terms of the solutes’ characteristics. New insights on the solution processes under scrutiny are presented. |
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