1,2-sulfanyl group migration as a driving force: new approach to pyrroles by reaction of allenic aldehydes with amines |
| |
| Authors: | Peng Lingling Zhang Xiu Ma Jie Zhong Zhenzhen Wang Jianbo |
| |
| Institution: | Beijing National Laboratory of Molecular Sciences (BNLMS), Green Chemistry Center (GCC) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China. |
| |
| Abstract: | reaction: see text] Acid-promoted reaction of sulfanyl group substituted allenic aldehyde with amine affords pyrrole derivatives in high yields. The neighboring group participation of the sulfanyl group is the driving force in this transformation. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
