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Bamboo-shaped carbon tubes from coal
Institution:1. Carbon Research Laboratory, Department of Materials Science and Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, P.O. Box 49, Dalian 116012, China;2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, P.O. Box 165, Taiyuan, Shanxi 030001, China;1. Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao, 266042, PR China;2. School of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao, 266109, PR China;3. Advanced Research Institute for Multidisciplinary Science, Qilu University of Technology, Jinan, 250353, Shandong Province, PR China;1. College of Materials, Fujian Key Laboratory of Advanced Materials, Xiamen University, Xiamen, Fujian 361005, PR China;2. College of Materials, Key Laboratory of High Performance Ceramic Fibers, Ministry of Education, Xiamen University, Xiamen, Fujian 361005, PR China;3. State Key Laboratory High Performance Ceramics & Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, PR China;1. Department of Organic Chemistry, Institute of Molecular and Translational Medicine, Faculty of Science, University of Palacky, 17. listopadu 12, 771 46 Olomouc, Czech Republic;2. Institute of Molecular and Translational Medicine, Faculty of Medicine and Dentistry, Palacky University and University Hospital in Olomouc, Hněvotínská 5, CZ-775 15 Olomouc, Czech Republic
Abstract:Bamboo-shaped carbon tubes (BCTs) were first synthesized in high yields from iron-loaded carbon electrodes prepared from coal by arc discharge. The BCTs were characterized by scanning electron microscopy and transmission electron microscopy (TEM). The TEM characterization reveals that the tubes have bamboo-like structures consisting of hollow compartments separated with conical shaped graphite layers. The diameters of BCTs are in the range of 40–60 nm with their length being about several micrometers. For some BCTs, the hollow compartments are quite uniform with a size of 100 nm. A growth model is suggested to explain the formation of bamboo structure in tubes.
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