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Solubilities of l-glutamic acid, 3-nitrobenzoic acid,p-toluic acid,calcium-l-lactate,calcium gluconate,magnesium-dl-aspartate,and magnesium-l-lactate in water
Institution:1. Department of Chemical Engineering, Negev Academic College of Engineering, Beer Sheva, Israel;2. Department of Chemical Engineering, Ben Gurion University of the Negev, Beer Sheva, Israel;1. State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;2. Collaborative Innovation Center of Chemical Science and Chemical Engineering of Tianjin, Tianjin University, China;3. Lionco Pharmaceutical Group, Haikou, Hainan 570100, China;1. School of Chemical Engineering and Technology, North University of China, Taiyuan 030051, China;2. Beijing Fukangren Biopharmaceutical Technology Co., Ltd. Jinan Branch, Jinan 250307, China
Abstract:Solubilities of l -glutamic acid, 3-nitrobenzoic acid, p -toluic acid, calcium-l -lactate, calcium gluconate, magnesium- dl -aspartate, and magnesium- l -lactate in water were determined in the temperature range 278 K to 343 K. The apparent molar enthalpies of solution at T =  298.15 K as derived from these solubilities areΔsolHm (l -glutamic acid,msat =  0.0565 mol · kg ? 1)  =  30.2 kJ · mol ? 1,ΔsolHm (3-nitrobenzoic acid, m =  0.0188 mol · kg ? 1)  =  28.1 kJ · mol ? 1, ΔsolHm( p - toluic acid, m =  0.00267 mol · kg ? 1)  =  23.9 kJ · mol ? 1,ΔsolHm (calcium- l -lactate tetrahydrate,m =  0.2902 mol · kg ? 1)  =  25.8 kJ · mol ? 1,ΔsolHm (calcium gluconate, m =  0.0806 mol · kg ? 1)  =  22.1 kJ · mol ? 1, ΔsolHm(magnesium-dl -aspartate tetrahydrate, m =  0.1469 mol · kg ? 1)  =  11.5 kJ · mol ? 1, andΔsolHm (magnesium- l -lactate trihydrate,m =  0.3462 mol · kg ? 1)  =  3.81 kJ · mol ? 1.
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