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Growth of long CdS nanowires using a carboxylic acid-functionalized self-assembled monolayer as substrate
Institution:1. Songshan Lake Materials Laboratory, Dongguan, Guangdong, 523808, China;2. Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, CAS, Beijing, 100190 China;3. Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong, 999077, China;1. Advanced Energy Storage Technology Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China;2. Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, China;3. Low-Dimensional Energy Materials Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China;4. Center of Super-Diamond and Advanced Film (COSDAF), City University of Hong Kong, Kowloon, Hong Kong, SAR 999077, China;5. Key Laboratory of Advanced Materials Processing & Mold, Ministry of Education, Zhengzhou University, Zhengzhou 450002, China;1. Tianjin Key Laboratory of Advanced Functional Porous Materials, Institute for New Energy Materials and Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China;2. The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
Abstract:We report a novel result that long CdS nanowires with typical width of 70–80 nm and length ranging from several micrometers to tens of micrometers can be obtained by the in situ growth on substrate of a carboxylic acid-functionalized self-assembled monolayer (SAM), which formed from a rigid aromatic molecule on mica surfaces. The as-grown CdS nanowires were characterized by X-ray photoelectron spectroscopy (XPS), Transmission electron microscopy (TEM) and Energy-dispersive X-ray spectroscopy (EDS). A possible mechanism that accounts for the formation of the one-dimensional (1D) nanowires was also discussed.
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