In situ polymerisation of monomers in layered double hydroxides |
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Affiliation: | Laboratoire des matériaux inorganiques (UMR 6002 CNRS), université Blaise-Pascal, 63177 Aubière cedex, France |
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Abstract: | Vinyl or amino-benzene sulfonates (VBS and ABS) are polymerised in situ after a soft thermal treatment (T = 473 K) between the sheets of layered double hydroxides (LDH). The reaction of polymerisation is studied either by 13C CP- MAS NMR or ESR spectroscopies. The resonance peak associated to the vinyl group disappears from the VBS/LDH hybrid material, and conversely, a narrow signal, characteristic of free radicals, is observed for the ABS/LDH system. To cite this article: E.M. Moujahid, C. R. Chimie 6 (2003). |
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