Synthesis and reactions of thiophene sulfides. Communication 40. An unusual reaction of 2,5-bis(methylthio)-3,4-bis(o-hydroxyphenyliminomethyl)thiophene |
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| Authors: | Ya L Gol'dfarb M A Kalik V S Bogdanov V K Zav'yalova |
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| Institution: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions In polar solvents (ethanol and chloroform), 2,5-bis(methylthio)-3,4-bis-(o-hydroxyphenyliminomethyl) thiophene undergoes intramolecular rearrangement to 2,5-bis(methylthio)-3-(2 -benzoxazolyl)-4-(o-hydroxyphenylaminomethyl) thiophene.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2750–2753, December, 1985. |
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