Homogeneous catalysts for dioxygen evolution from water. Water oxidation by trisbipyridylruthenium(III) in the presence of cobalt, iron and copper complexes |
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| Authors: | G L Elizarova L G Matvienko N V Lozhkina V N Parmon and K I Zamaraev |
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| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | Complexes of Co, Cu and Fe with bipyridyl, and cobalt complexes with ammonia, ethylenediamine and oxyacids are shown to be efficient catalysts for water oxidation by Ru(bpy)
3
3+
in both alkaline and weakly acidic media. Partially hydrolyzed forms of these complexes are assumed to be active.
      ,                 Ru(bpy)
3
3+
  ,    Co, Cu Fe,  , .  ,  .
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