| 含二苯联噁二唑大环多胺及其配合物的合成 |
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| 引用本文： | 孟鸿,花文廷.含二苯联噁二唑大环多胺及其配合物的合成[J].有机化学,1998(2). |
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| 作者姓名： | 孟鸿 花文廷 |
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| 作者单位： | 北京大学化学系，北京大学化学系 北京 100871，北京 100871 |
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| 摘 要： | 用2,5-双-(间甲酰基苯基)-1,3,4-噁二唑和相应的二胺,经2 2]缩合环化反应,合成了三个含二苯联噁二唑的新型大环多胺4、5和7以及5的钡络合物。
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| 关 键 词： | 1 3 4-噁二唑 大环多胺 |
The Synthesis and Structure of Aromatic Heterocyclic New Type Macrocyclic Compounds II The Synthesis of 1,3,4 - Oxadiazoles Macrocyclic Polyamine and It's Metal Complex |
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| MENG Hong,HUA Wen-Ting.The Synthesis and Structure of Aromatic Heterocyclic New Type Macrocyclic Compounds II The Synthesis of 1,3,4 - Oxadiazoles Macrocyclic Polyamine and It's Metal Complex[J].Chinese Journal of Organic Chemistry,1998(2). |
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| Authors: | MENG Hong HUA Wen-Ting |
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| Abstract: | 2 2] Condensation of two moleculars of 2,5 - bis - (m - formylphenyl -1,3,4-oxadiazole with two moleculars of diamines (ethylenediamine, diethylenetriamine and o - phenylenedi-amine) yield macrocyclic polyamines 4, 5 and 7 respectively. The reversible intercon - version of 5 and 6 has been established by 13 C NMR . The complexe 8 was obtained from the reaction of 5 with Ba(aO4)2 in CH2Cl2 - H2O. |
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| Keywords: | 1 3 4 - oxadiazole rnacrocyclic polyamine complex synthesis |
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