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X-ray photoelectron spectroscopy of sodium phosphate glasses
Authors:R. Gresch  W. Müller-Warmuth  H. Dutz
Affiliation:Institut für Physikalische Chemie der Universität Münster, Germany;Jenaer Glaswerk Schott Gen., Mainz, Germany
Abstract:X-ray photoelectron spectroscopy (XPS, ESCA) has been applied to sodium phosphate glasses with compositions between 15 and 50 mol% Na2O and for the purpose of comparison also to crystalline compounds containing oxygen and phosphorus. From the measurements a discrimination between bridging and non-bridging oxygen atoms was possible. The method provides a quantitative technique for structural analysis of phosphate glasses.
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