The inductively coupled plasma spectrum of OD in the infrared |
| |
| Authors: | Mark C Abrams Sumner P Davis M L P Rao Rolf Engleman |
| |
| Institution: | (1) Department of Physics, University of California at Berkeley, 94720 Berkeley, California, USA;(2) Present address: ATMOS Data Analysis Facility, Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, 91109 Pasadena, CA, USA;(3) Present address: Physics Department, Andhra University, 530 003 Waltair, India;(4) Department of Chemistry, University of Arizona - Tucson, 85721 Tucson, Az., USA |
| |
| Abstract: | To gain more information about the highly excited rotational states of the Δv = 1 sequence of OD vibration-rotation bands, the spectrum has been produced in an inductively coupled plasma discharge and
measured with a Fourier transform spectrometer between 1670 and 5768 cm−1. Along with the extension of 1–0 band, we have been successful in recording the 2–1 band for the first time. A nonlinear
least square fit of these bands yielded equilibrium molecular parameters forv = 0, 1 and 2 levels with a standard deviation of 0·0032 cm−1. The centrifugal distortion parameters show a systematic vibrational dependence. |
| |
| Keywords: | OD rot-vib spectrum ICP discharge centrifugal distortion constants |
| 本文献已被 SpringerLink 等数据库收录！ |
|
