Spontaneously aggregated chiral nanostructures from achiral tripod-terpyridine |
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| Authors: | He Xiaorong Li Qikai Li Yuliang Wang Ning Song Yabin Liu Xiaofeng Yuan Mingjian Xu Wei Liu Huibiao Wang Shu Shuai Zhigang Zhu Daoben |
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| Affiliation: | Beijing National Laboratory for Molecular Science (BNLMS), CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People's Republic of China. |
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| Abstract: | A chiral tripod-terpyridine ligand is known to coordinate with Ag+. These complexes self-assemble into chiral aggregates at room temperature. Molecular dynamic simulation reveals the cooperation of tripodal ligand structures with Ag(I) cations, which leads to the formation of helical aggregations, thus the chirality. |
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