Kinetics of the Interaction of O2 with Mo(V) Oxo Complexes on Silica Gel in Outer-Sphere Electron Transfer |
| |
| Authors: | Tret'yakov V. P. |
| |
| Affiliation: | (1) L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg Vul., 83114 Donets'k, Ukraine |
| |
| Abstract: | The kinetics of the interaction of Mo5+ oxo complexes on SiO2 with dioxygen distributed among the gas phase, silica gel, and complexes was examined using the relationship between the reaction rate constants ke and rate constant for substrate consumption km in a closed reactor. The kinetic criteria are given for selection of the mechanism for the photochemical and thermal reactions with a collisional or equilibrium intermediate. |
| |
| Keywords: | kinetics rate constants adsorption silica gel molybdenum(V) complexes dioxygen reaction mechanisms |
| 本文献已被 SpringerLink 等数据库收录！ |
