Syntheses, crystal structures and properties of two nickel(II) coordination polymers constructed from 5-(isonicotinamido)isophthalic acid |
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| Authors: | Man-sheng Chen Yi-fang Deng Chun-hua Zhang Jin-sheng Xu Xue Nie Si-ping Tang |
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| Institution: | 1. Department of Chemistry and Materials Science, Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Hengyang, 421008, Hunan, China
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| Abstract: | Two Ni(II) metal–organic frameworks, Ni(INAIP)(DMF)]·0.5DMF and Ni(INAIP)(H2O)]·2H2O, have been synthesized by the reaction of 5-(isonicotinamido)isophthalic acid (H2INAIP) with NiSO4·6H2O using different reaction solvents. Single-crystal X-ray diffraction analysis indicates that Ni(INAIP)(DMF)]·0.5DMF has a twofold interpenetrated three-dimensional (3D) framework with sra topology, while Ni(INAIP)(H2O)]·2H2O has a two-dimensional (2D) network structure with a 4-connected (43·63) topology. In addition, the magnetic and adsorption properties of the complexes were explored. |
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