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Structural studies of amino acid complexes-Iexafs study of glutamic acid complex of copper
Authors:C K Bhaskare and S Y Kulkarni
Affiliation:(1) Department of Chemistry, Shivaji University, 416 004 Kolhapur, India
Abstract:The ambiguity in the assignment of stereochemistry and co-ordination to Cu(II) complexes can be resolved by using x-ray absorption spectroscopic technique. The difficulty in the structural assignment of the Cu-glutamate complex is studied in detail. The Cu-acetylacetonate complex has also been studied as an example of square planar geometry. The Cu-glutamate complex is a distorted octahedral molecule.
Keywords:X-ray absorption spectra  EXAFS  distorted octahedral coordination  amino acid
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