Water clusters in supramolecular inclusion hydrates. Crystal structure of decaazatricyclo[28.2.2.213.16]tetratriacontane nanohydrate |
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| Authors: | Lipkowski J Simonov Yu A Lyuboradskii R Bourosh P N Popkov Yu A |
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| Institution: | (1) Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland;(2) Institute of Applied Physics, Moldova Academy of Sciences, Kishinev, Moldova;(3) Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine |
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| Abstract: | Inclusion compounds of solvate water molecules in a crystal matrix are investigated by X-ray diffraction analysis of a macrocyclic
polyamine decaazatricyclo28.2.2.213.16]tetratriacontane nanohydrate (I). When included in a crystal, water molecules are bonded by water-water (O-H...O) and water—macrocycle
(0-H...N and N-H...O) hydrogen bonds, forming a linear cluster.
Translated fromZhurnal Strukturnoi Khimii, Vol. 40, No. 5, pp. 993–1001, September–October, 1999. |
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