金属配合物和一氧化碳的反应

一氧化碳是发展可持续化学经济的重要原料。人们希望能够将一氧化碳催化转变成高附加值化学品,从而减少石油等化石资源对人类的束缚。研究均相金属配合物与一氧化碳的反应能够使人们了解一氧化碳转变及利用机理,并开发新催化剂高效地利用一氧化碳资源。本文从金属配合物与一氧化碳反应的活性点出发,分别讨论不同类型的金属配合物与一氧化碳的反应,以求让人们在分子水平上了解一氧化碳的基本反应原理;并总结了该领域存在的难点问题,展望了未来,希望更多的科研工作者投入其中,从而实现利用一氧化碳合成出各种各样的化学品和材料。

Reactions of Complexes and Carbon Monoxide

Carbon monoxide is an important feedstock in the development of a sustainable chemical economy. We hope to produce high value-added chemicals catalytically from carbon monoxide to reduce the ties to fossil fuels, such as petroleum. Studies on the reactions of homogeneous complexes and carbon monoxide could help us understand the principle of the transformation and utilization of carbon monoxide, and develop new catalysts to exploit carbon monoxide resource. In this review, the reactions of various kinds of complexes and carbon monoxide were discussed based on the reactive site of complexes to make us learn the fundamental principle of reactivities of carbon monoxide at the molecular level. The hard issues were also summarized in the hope of more researchers might be engaging in this fields to achieve the production of more chemicals using carbon monoxide.