Enantioselective total synthesis of eicosanoid and its congener, using organocatalytic cyclopropanation, and catalytic asymmetric transfer hydrogenation reactions as key steps |
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| Authors: | Kumaraswamy Gullapalli Padmaja Mogilisetti |
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| Affiliation: | Organic Division III, Fine Chemicals Laboratory, Indian Institute of Chemical Technology, Hyderabad-500 607, India. gkswamy_iict@yahoo.co.in |
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| Abstract: | An enantioselective unified strategy for the syntheses of the oxylipin class of natural products was accomplished. Our strategy relies on three catalytic steps: (a) organocatalytic cyclopropanation, (b) the catalytic asymmetric transfer hydrogenation (CATHy) reaction, and (c) the Nozaki-Hiyama-Kishi reaction. |
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