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On-wire lithography-generated molecule-based transport junctions: a new testbed for molecular electronics
Authors:Chen Xiaodong  Jeon You-Moon  Jang Jae-Won  Qin Lidong  Huo Fengwei  Wei Wei  Mirkin Chad A
Affiliation:Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
Abstract:On-wire lithography (OWL) fabricated nanogaps are used as a new testbed to construct molecular transport junctions (MTJs) through the assembly of thiolated molecular wires across a nanogap formed between two Au electrodes. In addition, we show that one can use OWL to rapidly characterize a MTJ and optimize gap size for two molecular wires of different dimensions. Finally, we have used this new testbed to identify unusual temperature-dependent transport mechanisms for alpha,omega-dithiol terminated oligo(phenylene ethynylene).
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