| 2-甲基-7-亚甲基-1,4,6-三氧螺[4,4]壬烷与丙烯腈、丙烯酸甲酯的共聚合反应及竞聚率的测定 |
| |
| 引用本文： | 潘才元 ,吴承佩 ,王寅,Toshiyuki Uryu. 2-甲基-7-亚甲基-1,4,6-三氧螺[4,4]壬烷与丙烯腈、丙烯酸甲酯的共聚合反应及竞聚率的测定[J]. 功能高分子学报, 1992, 0(4) |
| |
| 作者姓名： | 潘才元 吴承佩 王寅 Toshiyuki Uryu |
| |
| 作者单位： | 中国科学技术大学材料科学与工程系，中科院中国科技大学结构分析开放实验室，Institute of Industrial Science，University of Tokyo，Roppongi，Minato-ku，Tokyo 106，Japan |
| |
| 摘 要： | 用高效液相色谱跟踪2-甲基-7-亚甲基-1,4,6-三氧螺[4,4]壬烷(MMTN)与丙烯腈(AN),丙烯酸甲酯(MA)的共聚合反应。根据Lowry-Meyer共聚积分方程式,采用插值法进行数据拟合测定单体的竞聚率。对于体系MMTN(M_1)-AN(M_2),r_1=0.048;r_2=0.213;MMTN(M_1)-MA(M_2)r_1=0.025,r_2=0.764。说明两组共聚体系均有较强的交替共聚趋势。
|
| 关 键 词： | 2-甲基-7亚甲基-1 4.6-二氧螺[4 4]壬烷 共聚合反应 竞聚率测定 |
Copolymerization of 2-Methyl-7-Methylene-1, 4, 6-Troxaspiro (4,4) Nonane with Acrylonitrile, Methyl Acrylate and Measurement of Monomer Reactivity Ratioes |
| |
| Pan Caiyuan,Wu Chengpei,Wang Yin,Toshiyuki Uryu. Copolymerization of 2-Methyl-7-Methylene-1, 4, 6-Troxaspiro (4,4) Nonane with Acrylonitrile, Methyl Acrylate and Measurement of Monomer Reactivity Ratioes[J]. Journal of Functional Polymers, 1992, 0(4) |
| |
| Authors: | Pan Caiyuan Wu Chengpei Wang Yin Toshiyuki Uryu |
| |
| Affiliation: | Pan Caiyuan,Wu Chengpei,Wang Yin,Toshiyuki Uryu Department of Materials Science and Engineering,University of Science and Technology of China,Hefei,Anhui Institute of Industrial Science,University of Tokyo,Roppongi,Minato-ku,Tokyo 106,Japan |
| |
| Abstract: | The copolymerization of 2--methyl--7--methylene--1,4, 6,--trioxaspiro(4,4) nonane (MMTN) with acrylonitrile (AN), methyl acrylate (MA) was fol-lowed by high pressure liquid chromatography. The monomer reactivity ratioes werecalculated with the method of interpolation, based on Lowry-Meyer intergrationequation of copolymerization. For system of MMTN (M_1)--AN (M_2),r_1=0.048,r_2=0.213; for MMTN (M_1) --MA (M_2), r_1=0.025, r_2=0.764. The reshlts dem-onstrate the strong tendency of alternatihg copolymerization between MMTN--AN orMMTN--MA, which was discussed in detail. |
| |
| Keywords: | 2-methyl-7-methylene-1 46-trioxaspiro(4 4) nonane copolymerization measurement of reactivity ratioes |
| 本文献已被 CNKI 等数据库收录！ |
|
