N,N'-Dicyanoquinone diimide-derived donor-acceptor chromophores: conformational analysis and optoelectronic properties |
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Authors: | Chiu Melanie Jaun Bernhard Beels Marten T R Biaggio Ivan Gisselbrecht Jean-Paul Boudon Corinne Schweizer W Bernd Kivala Milan Diederich François |
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Affiliation: | Laboratorium für Organische Chemie, ETH Zürich , H?nggerberg, 8093 Zürich, Switzerland. |
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Abstract: | A formal [2 + 2] cycloaddition-cycloreversion (CA-CR) between N,N'-dicyanoquinone diimides (DCNQIs) and electron-rich alkynes was explored, providing a new class of π-conjugated donor-acceptor chromophores. These DCNQI adducts exist in the solid state as single diastereoisomers, but as two interconverting diastereoisomers in solution. Solid- and solution-state evidence for intramolecular charge transfer (CT) was obtained; additionally, the DCNQI adducts exhibit positive solvatochromism and significant solution-state third-order polarizabilities. |
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