Thermal analysis of bis(tetraethylammonium) tetrachloroferrate(II) |
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| Authors: | Emilia Stycze&#x , Agnieszka Pattek-Janczyk, Maria Gazda, Wojciech K. J
wiak, Dariusz Wyrzykowski,Zygmunt Warnke |
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| Affiliation: | aFaculty of Chemistry, University of Gdańsk, Sobieskiego 18, 80-952 Gdańsk, Poland;bFaculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland;cFaculty of Physics and Mathematics, Technical University of Gdańsk, Narutowicza 11/12, 80-952 Gdańsk, Poland;dInstitute of General and Ecological Chemistry, Technical University of Łódź, Żwirki 36, 90-924 Łódź, Poland |
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| Abstract: | Thermal decomposition of bis(tetraethylammonium) tetrachloroferrate(II) has been studied using the TG-FTIR, TG–MS and DTA techniques. The measurements were carried out in an inert atmosphere over the temperature range of 293–1073 K. The solid products of the thermal decomposition were identified by the FT-FIR, Mössbauer spectroscopy as well as the X-ray powder diffractometry. The influence of the oxidation state and the nature of a metal on thermal transformation profiles of analogous complexes have been discussed. |
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| Keywords: | Tetrahalogenoferrates(II) Thermal decomposition Mö ssbauer spectroscopy |
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