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Iridium-catalyzed asymmetric hydrogenation of imines in supercritical carbon dioxide using phosphite-type ligands |
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| Authors: | Sergey E. Lyubimov Eugenie A. RastorguevPavel V. Petrovskii Elena S. KelbyshevaNikolay M. Loim Vadim A. Davankov |
| Affiliation: | A. N. Nesmeyanov-Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Street 28, 119991 Moscow, Russia |
| Abstract: | A series of chiral phosphite-type ligands has been evaluated in the iridium-catalyzed asymmetric hydrogenation of acyclic arylimines in supercritical CO2. High reactivities (100% conversion in 50-120 min) and enantioselectivities (up to 95%) were obtained. |
| Keywords: | Enantioselective hydrogenation Supercritical carbon dioxide Imines Iridium |
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