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Copper Keplerates: High‐Symmetry Magnetic Molecules
Authors:Dr. Maria A. Palacios  Dr. Eufemio Moreno Pineda  Dr. Sergio Sanz  Dr. Ross Inglis  Dr. Mateusz B. Pitak  Dr. Simon J. Coles  Dr. Marco Evangelisti  Prof. Hiroyuki Nojiri  Christian Heesing  Prof. Euan K. Brechin  Prof. Jürgen Schnack  Prof. Richard E. P. Winpenny
Affiliation:1. EaStCHEM School of Chemistry, The University of Edinburgh, Edinburgh, UK;2. School of Chemistry, The University of Manchester, Manchester, UK;3. Institute of Nanotechnology, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen, Germany;4. EPSRC National Crystallography Service & Southampton Diffraction Centre, Chemistry, Faculty of Natural & Environmental Sciences, University of Southampton, Highfield, Southampton, UK;5. Instituto de Ciencia de Materiales de Aragón and Departamento de Física de la Materia Condensada, CSIC-Universidad de Zaragoza, Zaragoza, Spain;6. Institute for Material Research, Tohoku University, Aoba-ku, Sendai, Japan;7. Faculty of Physics, University of Bielefeld, Bielefeld, Germany
Abstract:Keplerates are molecules that contain metal polyhedra that describe both Platonic and Archimedean solids; new copper keplerates are reported, with physical studies indicating that even where very high molecular symmetry is found, the low‐temperature physics does not necessarily reflect this symmetry.
Keywords:copper  cuboctahedron  frustration  keplerates  molecular symmetry
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