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Synthesis,Spectroscopic Characterization and Antitumor Activity in vitro of Organometallo Substituted Polyoxotungstates(RM)3P2W15—O59^n—(RM=CpTi,CpZr,C4H7O2Sn or C5H9O2Sn)
引用本文:王晓红,何江华,张荣昌,刘景福.Synthesis,Spectroscopic Characterization and Antitumor Activity in vitro of Organometallo Substituted Polyoxotungstates(RM)3P2W15—O59^n—(RM=CpTi,CpZr,C4H7O2Sn or C5H9O2Sn)[J].中国化学,2003,21(4):415-418.
作者姓名:王晓红  何江华  张荣昌  刘景福
作者单位:DepartmentofChemistry,NortheastNormalUniversity,Changchun,Jilin130024,China
基金项目:theNationalNaturalScienceFoundationofChina (No .2 0 1710 11)
摘    要:Tetrabutylammonium or potassium salts of organometalllic derivatives of lacunary polyanion (RM)3P2W15O59^n-(RM=CpTi,CpZr,C4H7O2Sn or C5H9O2Sn) have been prepared and structurally characterized by elemental analysis,IR,UV-Vis,^1H NMR and^183 W NMR spectroscopies.The title complexes exhibit antitumor activity in vitro.

关 键 词:抗癌抗菌素  抗癌活性  合成  结构  多氧钨酸盐

Synthesis, Spectroscopic Characterization and Antitumor Activity in vitro of Organometallo Substituted Polyoxotungstates (RM)_3P_2W_(15)-O_(59)~(n-) (RM=CpTi, CpZr, C_4H_7O_2Sn or C_5_H9O_2Sn)
Wang Xiao‐Hong,He Jiang‐Hua,Zhang Rong‐Chang,Liu Jing‐Fu.Synthesis, Spectroscopic Characterization and Antitumor Activity in vitro of Organometallo Substituted Polyoxotungstates (RM)_3P_2W_(15)-O_(59)~(n-) (RM=CpTi, CpZr, C_4H_7O_2Sn or C_5_H9O_2Sn)[J].Chinese Journal of Chemistry,2003,21(4):415-418.
Authors:Wang Xiao‐Hong  He Jiang‐Hua  Zhang Rong‐Chang  Liu Jing‐Fu
Abstract:Tetrabutylammonium or potassium salts of organometalllic derivatives of lacunary polyanion (RM) 3P 2W 15 O n- 59 (RM=CpTi, CpZr, C 4H 7O 2Sn or C 5H 9O 2Sn) have been prepared and structurally characterized by elemental analysis, IR, UV vis, 1H NMR and 183 W NMR spectroscopies. The title complexes exhibit antitumor activity in vitro.
Keywords:organometallic derivative of polyoxometalate  Dawson structure  antitumor activity
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