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Estimation of the minimum pore size sufficient for capillary hysteresis
Authors:Yu K Tovbin  A G Petukhov
Institution:(1) State Scientific Center “L. Ya. Karpov Physicochemical Research Institute”, 10 ul. Vorontsovo pole, 103064 Moscow, Russian Federation
Abstract:A procedure for determination of the minimum pore sizes suitable for the formation of an adsorption-desorption hysteresis loop was developed. Conditions for the formation of hysteresis in infinite rectangular channels and in the cavities restricted along three directions (spheres, rectangular parallelepipeds) and in channels with different cross-sections and limited lengths are considered. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 18–28, January, 2008.
Keywords:adsorption isotherm  hysteresis  phase diagrams  cylindrical pores  slit-shaped pores  spherical cavities  rectangular channels  lattice-gas model
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