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Reliable, rapid and simple voltammetric detection of urea nitrate explosive
Authors:Cagan Avi  Lu Donglai  Cizek Karel  La Belle Jeff  Wang Joseph
Institution:The Biodesign Institute and Departments of Chemical Engineering and Chemistry, Arizona State University, Tempe, AZ 85287-5801, USA.
Abstract:A highly selective and rapid electrochemical assay of the improvised explosive urea nitrate (UN) is reported. The method involves a short ( approximately 10 s) acid-catalyzed reaction of UN with 4-nitrotoluene (NT) followed by a rapid ( approximately 2 s) square-wave voltammetric (SWV) detection of the 2,4-dinitrotoluene (DNT) product. The new protocol offers great promise for a reliable field detection of UN, with significant advantages of speed, sensitivity, portability, simplicity, and cost.
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